Baking soda is sodium bicarbonate NaHCO3, an alkali. It exists naturally, for example dissolved in the water of thermal springs. It will begin acting immediately in the presence of an acid, which means you need to act quickly with recipes that rely on it alone. While buttermilk, citrus and yogurt are obvious triggers, baking employs a variety of other acidic ingredients, including honey, brown sugar, molasses and chocolate.
Baking powder is an all-in-one leavener, containing baking soda and a precise amount of acid to use up all the soda. It begins reacting when liquid is added to it. Baking powder includes cornstarch, which helps absorb moisture to moderate the leavening reaction.
How they work
Both react to release carbon dioxide (CO2). Importantly, they only enlarge bubbles that already exist in the dough. They do not create a single new bubble. That means that adding them to your dough or batter won’t automatically make them rise. You must pay attention to the mixing method in a recipe, such as creaming butter and sugar, beating eggs, or turning over your dough to create the air bubbles the leavener will inflate. Note that it is easy to over-leaven. The CO2 bubbles get big, float to the top and pop, the baked goods get heavy and fall. And if you notice a soapy flavour that can mean too much baking soda or insufficiently mixed baking powder. Baking soda and baking powder are not interchangeable. In recipes with both the baking powder is doing the leavening while the baking soda helps neutralise acid in the dough so that doesn’t interfere with the baking powder. Reducing the acidity of the dough also helps it to brown by the Maillard reactions.
Rules of thumb
1 cup of flour can be leavened by ¼ teaspoon baking soda or 1 to 1¼ teaspoons of baking powder.
½ teaspoon of baking soda will neutralize 1 cup mildly acidic ingredient (sour cream, buttermilk) / 1 teaspoon of lemon juice / 1¼ teaspoons of cream of tartar.
You can make a crude baking powder replacement with 1 tb baking soda, 2 tablespoons cream of tartar and 1½ tb cornstarch
Baking soda and baking powder lose their potency over time so store in sealed containers. To test their viability, mix ¼ teaspoon baking powder into ½ cup very hot water or ¼ teaspoon baking soda into ½ cup very hot water mixed with ¼ teaspoon white vinegar. If you see fine bubbles, you’re good to go.
Source: Becky Crystal in The Washington Post